ISOTHERMAL AND BATCH ADSORPTION STUDIES OF MALACHITE GREEN OXALATE DYE ONTO ACTIVATED CARBON FROM SNAIL SHELL

Mr Ikhazuangbe Prosper Monday-ohien and Ikhazuangbe P.M.O., Eruotor M.O.   (Published 2017)

Mr Prosper Monday-ohien
See Profile Page

Abstract

Adsorption efficiency, kinetic and
thermodynamic studies of the adsorption of Malachite
green oxalate onto activated carbon from snail shell was
carried out. The cleaned Snail shell was carbonized at
400
oC, crushed and sieved before it was activated with 0.1m
HCl at 800
oC in a furnace. Batch adsorption experiment
was carried out at variable concentration, time and
temperature while other factors are kept constant. The
adsorption isotherms used show that the correlation
coefficient of Freundlich isotherm is closer to unity
compare to that of Langmuir isotherm. The adsorption
follows the Pseudo second order kinetic with adsorption
capacity of 1.7544 (mg/g) and rate constant of
0.471(g/mg.min). The thermodynamic parameters: change
in enthalpy,
?H = 15.90 KJ/mol, change in entropy ?S =
60.16J/mol. K and the change in Gibbs free energy
?G = -
1.69, -2.98, -3.64, -3.24, -3.43 and -3.51 KJ/mol at 303,
308, 313, 318, 323 and 328K respectively. These results
show that activated carbon from snail shell has the
potential of a good low cost adsorbent for the removal of
this hazardous dye from wastewater.

 


Item Type: Journal article(non-copyrighted)
Format: PDF document,   178.03 KB
Copyright: Creative Commons LicenseCreative Commons license
Keywords: Adsorption, kinetic, Malachite green oxalate, snail shell, thermodynamic
Department: Chemical Engineering
Field of Study: Engineering- Chemical
Uploaded By: Chukwuemeka Obasi Chijioke
Date Added: 12 Jan 2022 5:48am
Last Modified: 12 Jan 2022
Journal URL: https://www.edouniversity.edu.ng/oer/journal/isothermal_and_batch_adsorption_studies_of_malachite_green_oxalate_dye_onto_activated_carbon_from_snail_shell


Google Docs     Print     Download